ASRJC 2022 J2 H2Prelim P4 QP

ASRJC JC2 PRELIM 2022 9729/04/H2 [Turn Over ANDERSON SERANGOON JUNIOR COLLEGE 2022 JC 2 PRELIMINARY EXAMINATION NAME:________________________________ ( ) CLASS: 22 /____ CHEMISTRY 9729/04 Paper 4 Practical 25 August 2022 2 hours 30 minutes Candidates answer on the Question Paper. Additional Materials: As listed in the Confidential Instructions READ THESE INSTRUCTIONS FIRST Write your name, class and index number on all the work you hand in. Give details of the practical shift and laboratory where appropriate, in the boxes provided. Write in dark blue or black pen. You may use a HB pencil for any diagrams or graphs. Do not use staples, paper clips, glue or correction fluid. Answer all questions in the spaces provided on the Question Paper. The use of an approved scientific calculator is expected, where appropriate. You may lose marks if you do not show your working or if you do not use appropriate units. Quantitative Analysis Notes are printed on pages 23 and 24. Shift Laboratory At the end of the examination, fasten all your work securely together. The number of marks is given in brackets [ ] at the end of each question or part question. For Examiner’s Use 1 / 14 2 / 21 3 / 9 4 / 11 Total / 55 This document consists of 22 printed pages and 2 blank pages.

2 ASRJC JC2 PRELIM 2022 9729/04/H2 Answer all the questions in the spaces provided. 1 Determination of a value for an enthalpy change of solution by an indirect method FA 1 is solid sodium hydrogencarbonate, NaHCO3. FA 2 is 1.50 mol dm–3 sulfuric acid, H2SO4. Sodium hydrogencarbonate dissolves in water according to equation 1. equation 1 NaHCO3(s) + aq → Na+(aq) + HCO3–(aq) H1 Both solid and aqueous sodium hydrogencarbonate react with sulfuric acid. equation 2 2NaHCO3(s) + H2SO4(aq) → Na2SO4(aq) + 2H2O(l) + 2CO2(g) H2 equation 3 2NaHCO3(aq) + H2SO4(aq) → Na2SO4(aq) + 2H2O(l) + 2CO2(g) H3 In this question, you will perform an experiment to determine a value for H2. You will use data provided to calculate H3 and hence a value for H1. (a) Determination of the molar enthalpy change of reaction, H2 In this experiment, you will determine the maximum temperature change when a known mass of solid sodium hydrogencarbonate, FA 1, reacts with dilute sulfuric acid, FA 2. In an appropriate format in the space provided on page 3 , prepare tables in which to record for your experiment: • all weighings to an appropriate level of precision, • all values of temperature, T, to an appropriate level of precision. Procedure 1. Weigh the capped bottle containing FA 1. Record this mass. 2. Place one polystyrene cup inside another polystyrene cup and place both in a glass beaker. 3. Use a 25 cm3 measuring cylinder to transfer 25 cm 3 of FA 2 into the polystyrene cup. 4. Stir the FA 2 in the polystyrene cup with the thermometer. Read and record its initial temperature, Ti. 5. Slip the thermometer through the lid. Carefully transfer all the solid FA 1 in the bottle to the FA 2 in the polystyrene cup , in small portions , to avoid too much frothing. Secure the lid onto the cup. 6. Use the thermometer to stir the mixture . Observe the temperature until it shows the maximum change from the initial temperature. Record this temperature, Tm. 7. Reweigh the empty capped bottle. Record this mass. Determine the maximum temperature change, T, and the mass of FA 1 used. Results

3 ASRJC JC2 PRELIM 2022 9729/04/H2 [Turn Over [5] (b) In the following calculations, you should assume that the specific heat capacity of the solution is 4.18 J g–1 K–1, and the density of the solution is 1.00 g cm–3. (i) Use your results from 1(a) to calculate the heat change for your experiment. heat change = ………………………………………. [1] (ii) Hence, determine a value for H2. The sulfuric acid is in excess. Include the sign of H2 in your answer. [Ar: H, 1.0; C, 12.0; O, 16.0; Na, 23.0] H2 = ………………………………………. [1]

4 ASRJC JC2 PRELIM 2022 9729/04/H2 The results of an experiment where a solution of 0.690 mol dm −3 aqueous sodium hydrogencarbonate, NaHCO 3(aq) was reacted completely with an excess of dilute sulfuric acid, FA 2, are shown in Table 1.1. Table 1.1 volume of NaHCO3(aq) used / cm3 50.0 initial temperature of NaHCO3(aq) / oC 27.6 volume of FA 2 used / cm3 25.0 initial temperature of FA 2 / oC 31.2 minimum temperature / oC 28.4 (iii) Use the results given in Table 1.1 and the formula below to calculate the weighted average initial temperature, Tav, of the reaction mixture. The formula for Tav is given as Tav = (vol. of FA 2 × initial temp. of FA 2) + (vol. of NaHCO3 × initial temp. of NaHCO3) total volume of reaction mixture Tav = ………………………………………. [1] (iv) Hence, calculate a value for H3. H3 = ………………………………………. [4]

5 ASRJC JC2 PRELIM 2022 9729/04/H2 [Turn Over (c) Use your answers from 1(b)(ii) and 1(b)(iv) to calculate a value for H1 for the reaction shown in equation 1. If you are not able to determine a value for 1(b)(ii) and/or 1(b)(iv), you may use x and y to represent the respective enthalpy changes and proceed with this part of the question. H1 = ………………………………………. [2] [Total: 14]

6 ASRJC JC2 PRELIM 2022 9729/04/H2 2 To determine the order of reaction with respect to the concentration of iodine in the iodination of propanone reaction FA 3 is 1.00 mol dm–3 sulfuric acid, H2SO4. FA 4 is 1.00 mol dm–3 propanone, CH3COCH3. FA 5 is an aqueous solution of iodine, I2. FA 6 is 0.0100 mol dm–3 sodium thiosulfate, Na2S2O3. FA 7 is 0.50 mol dm–3 sodium hydrogencarbonate, NaHCO3. You are also provided with a starch indicator. The equation in reaction 1 represents the reaction between CH3COCH3 and I2. reaction 1: CH3COCH3(aq) + I2(aq) → CH3COCH2I(aq) + HI(aq) This reaction is first order with respect to both CH3COCH3 and H+ ions. You are to investigate the order of reaction with respect to I2. A reaction mixture containing an acidified solution of CH3COCH3 and I2 is first prepared. At timed intervals, aliquots (portions) of this reaction mixture will be removed and quenched using excess NaHCO3. It is not essential that you complete the titration of one aliquot before extracting the next one from the reaction mixture. However, you must ensure that each aliquot is mixed immediately with NaHCO3. The remaining amount o f I2 at different times can then be dete rmined by titration agains t Na2S2O3. Na2S2O3 reacts with I2 as shown in the equation in reaction 2. reaction 2: 2S2O32–(aq) + I2(aq) → 2I–(aq) + S4O62–(aq) The required order of reaction can be obtained by graphical analysis of your results. (a) Preparing and titration of the reaction mixture Notes: You will perform each titration once only. Great care must be taken that you do not exceed the end–point. Once you have started the stopwatch, it must continue running for the duration of the experiment. You must not stop the stopwatch until you have finished this experiment. You should aim to transfer your first aliquot approximately four minutes after starting the reaction. You should aim not to exceed a maximum reaction time of 20 minutes for this experiment. In an appropriate format in the space provided on page 8, prepare a table in which to record for each aliquot • the time of transfer, t, in minutes and seconds, • the decimal time, td, in minutes, to 0.1 min, for example , if t